Te tono o te hydroxypropyl hydroxypropyl methyl cellulose i roto i te whakaputa o te tohu polymerizatization o te polyvinyl chloride

Abstract: Te tono o te wharehydroxypropyl methylcelloseEngari ki te kawemai i tetahi ki te whakaputa PVC me te tohu o te polymerizatizatizatizatizatizer. Ko nga hua o nga momo e rua o te hydroxypropyl methylcellulose i runga i nga ahuatanga o te PVC me te tohu o te polymerizatizatizatization i tirotirohia. I whakaatuhia nga hua he mea taea ki te whakakapi i te hydroxypropy sydroxypropyl methyl hei kawemai i tetahi.

Teitei-o-polymerization Pvc Retins mo te PvC Retins me te taumata toharite o te polymerizatizatization i waenga i te ngota, ko te nuinga o te polymerizatizatizatizer o 2,500 [1]. I whakaritea ki te PVC noa Pvc noa, he nui te kaha o te Pvc Resin, he pai te whakaekenga o te riri, te aukati i te pakeke, te ngenge o te paoa me te aukati i te mate. He mea whakakapinga rapa pai ka taea te whakamahi i roto i nga miihini moana, nga waea me nga taura, nga hoia hauora, me etahi atu [2].

Ko te tikanga whakaputa o te PVC me te taumata tiketike o te polymerizatizatization ko te nuinga o te polymerization. I roto i te mahinga o te tikanga whakatārewatanga, ko te marara he kaihoko awhina nui, a ka pa te momo me te nui o te rahi o te matūriki, te tohatoha rahi rahi o te PVC kua oti. Ko nga punaha haumanu kua whakamahia ko te punaha waipiro polyvinyl me te methylcellulose me te miihini waipiro polyvinyl e whakamahi ana i te nuinga o te waa.

1 Nga taonga matua me nga whakaritenga

Ko nga rauemi mata matua me nga tohu i whakamahia i roto i te ripanga 1 Pepa.

2 ihirangi whakamatautau

2.. 1 Te whakarite i te otinga metylcellosel

Tangohia etahi wai whakaheke, whakauruhia ki roto i te ipu ka wera ki te 70 ° C, a ka uru haere te hydroxypropyl methylcellulose i raro i te whakaohooho. Ko te cellulose e rere ana i runga i te wai i te tuatahi, katahi ka marara noa atu ka tae noa ki te whakaranu. Whakamātauria te otinga ki te rōrahi.

Ripanga 1 Nga taonga matua matua me o raatau whakaritenga

Ingoa rauemi Raw

Tautanga

Vinyl groriade monomer

Kounga seaste≥99. 98%

Te wai e rongoa ana

Whakahaerehia≤10. 0 μs / cm, pH uara 5. 00 ki te 9. 00

Waipiro polyvinyl a

ALMALALEYSISED tohu 78. 5% ki te 81. 5%, ihirangi Ash≤0. 5%, he mea nui. 0%

Polyvinyl waipiro b

ALMALALELYISED tohu 71. 0% ki te 73. 5%, tirohia 4. 5 ki te 6. 5mba s, voolatile take. 0%

Polyvinyl waipiro c

ALMALALEYSISIGELIGE 54. 0% ki te 57. 0%, tirohia te 800 ~ 1 400mpa s, ihirangi totoro 39. 5% ki te 40. 5%

Pūmai i te hydroxypropyl methylcelllose a

Viscipoty 40 ~ 60 mpa s, te haangai papatipu mo te 28% ~ 30%, hydroxypropyl haangai 7% ~ 12%, makuku ≤5. 0%

Hydroxypropyl sompopropyl methylcelllose b

Viscipoty 40 ~ 60 mpa s, te haangai papatipu mo te 28% ~ 30%, hydroxypropyl haangai 7% ~ 12%, makuku ≤5. 0%

BIS (2-ethylhexyl peroxydicarbonate)

Te haangai papatipu [(45 ~ 50) ± 1]%

2.. 2 Tikanga Whakamatau

I runga i te taputapu whakamatautau iti 10, whakamahia te celluxypropy methyl methyl hei whakahaere i nga whakamatautau tohu tohu hei whakatau i te tauira iti o te whakamatautau iti; Whakamahia te Cellroxypropy a-roto o te whare miihini ki te whakakapi i te cellroxypropy methyl methyl hei whakamatautau; Ko nga hua o te PVC Restin i hangaia e te rereke o te hydroxypropy methyl cellulose i whakaritea ki te ako i te kaha whakakapi o te hydroxypropyl hydroxypropyl celdroxrose. E ai ki nga hua o te whakamatautau iti, ka whakatutukihia te whakamatautau whakaputa.

2. 3 Nga waahanga whakamatautau

I mua o te tauhohenga, horoia te polymerization Kuttle, kati te hinu o raro, tapiritia etahi atu o te wai e kainga ana, ka tapiritia te marara; Katihia te taupoki o te kettle, te waatea i muri i te paahitanga o te whakamatautau o te hauota, ka tapirihia a Vinyl Chloride monomer; I muri i te whakaohooho makariri, whakauruhia te kaiwhakamatautau; Whakamahia te wai e pa ana ki te whakaara i te pāmahana ki te pāmahana tauhohenga, ka taapirihia te otinga o te hammonium hei whakatika i te uara pH o te punaha tauhohenga; I te wa e heke ana te pehanga urupare ki te pehanga kua tohua i roto i te tauira, tapirihia he kaihoko whakamutu me te kaihoroi kua oti i a PvC Resin i te centrifugation me te whakamaroke, me te whakatauira mo te tātari.

2.. 4 Nga Tikanga Tātaritanga

E ai ki nga tikanga whakamatautau e whai kiko ana i roto i te Paerewa Taiao Q31 / 0116000823C0028, ko te tau tirotiro, he mea totika (tae atu ki te wai kirihou o te 100 g pfc o te 100. Ko te rahi o te matūriki toharite o te pvc resin i whakamatauria; Ko te morphology o nga matūriki PVC ka kitea ma te whakamahi i te whaikorero a te karahipi.

3 nga hua me te whakawhitinga korero

3

Press 2. E ai ki te tikanga whakamatautau i whakaahuahia i te 4, kua oti ia ia te puranga o te PvC iti-paku kua whakaatuhia, ka whakaatuhia nga hua i te Ripanga 2.

Ripanga 2 Nga Hua o nga Pakanga rereke o te whakamatautau iti

Paukena

Hydroxypropyl methyl cellulose

Te Whakanui / (G / ML)

Rahi matūriki toharite / μm

Tirohanga / (ml / g)

Te whakauru kirihou mo te 100 g Pvc Resin / g

Te take /%

1#

Whakauru

0.36

180

196

42

0.16

2#

Whakauru

0.36

175

196

42

0.20

3#

Whakauru

0.36

182

195

43

0.20

4#

Nō te kāinga

0.37

165

194

41

0.08

5#

Nō te kāinga

0.38

164

194

41

0.24

6#

Nō te kāinga

0.36

167

194

43

0.22

Ka kitea mai i te Ripanga 2: Ko te ahua o te ahua o te tirohanga me te kirihou i te PvC Resin e tika ana ma te whakamahi i nga momo cellullose mo te whakamatautau iti; Ko te hua o te Resin i whiwhi ma te whakamahi i te hydroxypropyl o te whare hydroxypropyl o te whare whatylcellulose tauira ko te rahi matūriki toharite he iti ake te paku.

Ko te Whakaahua 1 e whakaatu ana i nga whakaahua SEM o nga hua o te PVC Resin i whiwhi ma te whakamahi i nga momo wai hydroxypropyl.

methylcelllose1(1) -Ma -Tirohia te hydroxypropyl methylcellose

methylcelllose2(2)-2) -Maypropyy hydroxypropyl methylcellulose

Rarangi. 1 sem o te hinu i whakaputaina i roto i te 10-l polymerizer i te aroaro o te waikawa o te waikawa methyl cellulose

Ka kitea mai i te Whakaahua 1 ko nga hanganga o te mata o nga matūriki PVC e hangaia ana e nga kaimara o te cellulose rereke.

Ki te kohi, ka kitea pea ko te hydroxypropyl hydroxypropyl o te whare ka whakamatauhia i roto i tenei pepa te whakakii i te whakakapi i te hydroxypropyl kawemainsemailfrose.

3. 2 Ko te tātaritanga whakatairite mo te kounga o te PVC Resin me te tohu o te polymerizatizatizatizatizatization i te whakamatautau whakaputa

Na te nui o te utu me te tupono o te whakamatautau whakatipu, kaore e taea te whakamahi tika i te kaupapa whakakapinga iti. Na reira, ko te kaupapa o te whakapiki haere i te waahanga o te hydroxypropyl o te whare hydroxypropyl i roto i te tātai. Ko nga hua whakamatautau mo ia puranga e whakaatuhia ana i te Ripanga 3. Whakaatuhia.

Ripanga 3 Nga hua o te whakamatautauranga o nga puranga whakaputa rereke

Paukena

M (hydroxypropyl hydroxypropyl methyl cellulose): m (m (kawemai i te hydroxypropyl methyl cellulose)

Te Whakanui / (G / ML)

Tau Tirohanga / (ML / G)

Te whakauru kirihou mo te 100 g Pvc Resin / g

Te take /%

0#

0: 100

0.45

196

36

0.12

1#

1.25: 1

0.45

196

36

0.11

2#

1.25: 1

0.45

196

36

0.13

3#

1.25: 1

0.45

196

36

0.10

4#

2.50: 1

0.45

196

36

0.12

5#

2.50: 1

0.45

196

36

0.14

6#

2.50: 1

0.45

196

36

0.18

7#

100: 0

0.45

196

36

0.11

8#

100: 0

0.45

196

36

0.17

9#

100: 0

0.45

196

36

0.14

Ka kitea mai i te Ripanga 3 ko te whakamahinga o te hydroxypropyl hydroxycroplose i tino piki haere tae noa ki te whakakapi i nga purongo o te hydroxypropyl o te whare hydroxyprolllose kawemai. Ko nga tohu matua penei i te haangai kirihou me te kitea i te nuinga o te waa, e whakaatu ana i te kohinga hydroxypropyl o te whare ka taea te whakakapi i te methylcroplulose i roto i tenei pepa.

4 Te Whakamutunga

Te whakamatautau o te wharehydroxypropyl methyl celluloseI runga i te 10 l o te taputapu whakamatautau iti e whakaatu ana kei a ia te mea tika ki te whakakapi i te cellroxypropy methyl cellulose; Ko nga hua whakamatautau whakakapinga whakaputa e whakaatu ana ko te Cellroxyprop homexyprose a-whare e whakamahia ana mo te PVC Ringa, nga tohu kounga nui o te pvc resin kua oti, kaore he rereketanga o te cellulose. I tenei wa, ko te utu o te cellulose o te whare i te maakete he iti ake i te waa o te cellulose kawemai. Na, ki te whakamahia te cellulose a-whare i roto i te mahi, ka taea te whakaheke i nga utu o nga taonga whakaputa.


Te wa tuku: Apr-25-2024