I-Diacetone Acrylamide (DAAM) iyi-monomer eguquguqukayo esetshenziswa ezinqubweni ezahlukahlukene ze-polymerization ukukhiqiza ama-resin, okokunamathela, okunamathelayo, nezinye izinto ezidinga ukuqina okushisayo okuthuthukisiwe, ukumelana kwamanzi, nezakhiwo zokunamathela. I-DAAM igqama ngenxa yesakhiwo sayo samakhemikhali esiyingqayizivele kanye nekhono lokubhekana nokuhlangana okuhlanganayo nezinye izinhlanganisela, njenge-adipic dihydrazide (ADH), okuholela ezintweni ezisebenza kahle kakhulu.
I-Chemical Properties ye-DAAM
- Igama le-IUPAC:I-N-(1,1-Dimethyl-3-oxo-butyl)acrylamide
- I-Chemical Formula:I-C9H15NO2
- Isisindo se-Molecular:169.22 g/mol
- Inombolo ye-CAS:2873-97-4
- Ukubukeka:I-crystalline emhlophe eqinile noma impushana
- Ukunyibilika:Incibilika emanzini, i-ethanol, nezinye izincibilikisi ze-polar
- I-Melting Point:53°C kuya ku-55°C
Amaqembu Asebenzayo Abalulekile
- Iqembu le-Acrylamide:Inikela ku-polymerizability ngokusabela kwama-radical mahhala.
- Iqembu le-Ketone:Ihlinzeka ngeziza ezisebenzayo zokuxhumanisa nezinhlanganisela ezifana nama-hydrazines.
Ukuhlanganiswa kwe-DAAM
I-DAAM ihlanganiswa ngokusabela kwe-diacetone alcohol ne-acrylonitrile, ilandelwa yisinyathelo se-catalytic hydrogenation noma i-hydrolysis ukwethula iqembu le-amide. Inqubo yokukhiqiza iqinisekisa umkhiqizo ohlanzekile ofanele izicelo zezimboni.
Izinyathelo Ezibalulekile Zokusabela:
- I-Diacetone Alcohol + Acrylonitrile → Inhlanganisela Ephakathi
- I-Hydrogenation noma i-Hydrolysis → I-Diacetone Acrylamide
Izicelo ze-DAAM
1. Izinamathiselo
- Iqhaza le-DAAM:Ithuthukisa izakhiwo zokubopha ngokuphromotha ukuxhumanisa kanye nokuzinza kwe-thermal.
- Isibonelo:Izinamathiselo ezizwela ukucindezela ezinamandla athuthukisiwe wekhasi nokuqina.
2. Izigqoko Zamanzi
- Iqhaza le-DAAM:Isebenza njenge-ejenti yokwenza ifilimu enikeza ukumelana kwamanzi okuhle kakhulu nokuguquguquka.
- Isibonelo:Amapende okuhlobisa kanye nezimboni zokugqwala nokumelana nokugqoka.
3. Izindwangu zokuqeda ama-ejenti
- Iqhaza le-DAAM:Inikeza ukuqedwa kokucindezela okuqinile kanye nezakhiwo zokunqanda imibimbi.
- Isibonelo:Sebenzisa ekuqedeni okungeyona i-iron ezindwangu.
4. Ama-Hydrogel kanye nezicelo ze-Biomedical
- Iqhaza le-DAAM:Inomthelela ekwakhiweni kwama-hydrogel ahambisanayo.
- Isibonelo:Amasistimu okulethwa kwezidakamizwa alawulwayo.
5. Iphepha nokupakisha
- Iqhaza le-DAAM:Inikeza amandla athuthukisiwe kanye nezakhiwo zokuvimbela umswakama.
- Isibonelo:Izingubo zephepha ezikhethekile zokupakisha ukudla nesiphuzo.
6. Ama-sealants
- Iqhaza le-DAAM:Ithuthukisa ukuguquguquka nokumelana nokuqhekeka ngaphansi kwengcindezi.
- Isibonelo:Ama-sealant ashintshwe nge-silicone okwakhiwa kanye nezicelo zezimoto.
Izinzuzo Zokusebenzisa i-DAAM
- Amandla Okuxhumanisa Okuhlukahlukene:Yakha amanethiwekhi aqinile anama-cross-linkers asuselwa ku-hydrazide njenge-ADH.
- Ukuqina Kokushisa:Iqinisekisa ubuqotho ngaphansi kwezimo zokushisa eziphezulu.
- Ukumelana Nomswakama:Idala amafilimu nezakhiwo ezixosha amanzi.
- Ubuthi obuphansi:Kuphephile ukusebenzisa uma kuqhathaniswa namanye ama-monomers.
- Ukuhambisana Okubanzi:Isebenza ngamasu ahlukahlukene we-polymerization, kufaka phakathi i-emulsion, ukumiswa, nezinqubo zesixazululo.
Ukuhambisana ne-Adipic Dihydrazide (ADH)
Inhlanganisela ye-DAAM ne-ADH isetshenziswa kakhulu ezinhlelweni ze-polymer ezixhumene. Ukusabela phakathi kweqembu le-ketone le-DAAM neqembu le-hydrazide ku-ADH kuphumela ekuxhumekeni okuhlala isikhathi eside kwe-hydrazone, okuvumela:
- Amandla emishini athuthukisiwe.
- Ukumelana nokushisa okuphezulu.
- Ukuvumelana nezimo kuye ngezidingo zokwakheka.
Indlela yokusabela:
- Ukusebenzisana kweKetone-Hydrazide:I-DAAM + ADH → I-Hydrazone Bond
- Izicelo:Izembatho ze-polyurethane ezitholakala emanzini, izinto zokuziphilisa, nokunye.
I-Market Insights namathrendi
Isidingo Somhlaba Wonke
Imakethe ye-DAAM ibone ukukhula okubonakalayo ngenxa yokwanda kokusetshenziswa kwayo ekwenziweni kwe-eco-friendly, emanzini kanye nezinhlelo ze-polymer eziphambili. Izimboni ezifana nezezimoto, ezokwakha, neze-elekthronikhi ziqhuba isidingo sezixazululo ezisekelwe ku-DAAM.
Ukuqamba
Intuthuko yakamuva igxile kulokhu:
- Ezinye izindlela ezisekelwe ku-Bioo:Ukuhlanganiswa kwe-DAAM kusuka kuzinsiza ezivuselelekayo.
- Ama-Coatings Asebenza Kakhulu:Ukuhlanganiswa kumasistimu we-nanocomposite ukuze kuthuthukiswe izakhiwo ezingaphezulu.
- Ukupakisha Okusimeme:Sebenzisa emixubeni ye-polymer e-biodegradable.
Ukuphatha kanye Nesitoreji
- Izinyathelo Zokuphepha:Gwema ukuhogela noma ukuthinta isikhumba; sebenzisa izinto zokuzivikela ezifanele (i-PPE).
- Imibandela Yesitoreji:Gcina endaweni epholile, eyomile, futhi enomoya omuhle; gwema ukuchayeka kumswakama nokushisa.
- Impilo Yeshelufu:Ivamise ukuzinza kufikela ezinyangeni ezingama-24 ngaphansi kwezimo ezinconyiwe.
I-Diacetone Acrylamide (DAAM) iyi-monomer ebalulekile kusayensi yezinto zesimanje, enikeza izakhiwo ezihlukile eziyenza ibaluleke kakhulu ezinhlelweni zokusebenza ezisebenza kahle. Kusukela ekhonweni layo lokuxhumanisa elishintshashintshayo ukuya ekusetshenzisweni kwayo okubanzi, i-DAAM iyaqhubeka nokubamba iqhaza elibalulekile ekuthuthukiseni izinto ezinamathelayo, okokunamathelayo, namapholymeri. Ukuhambisana kwayo nobuchwepheshe obuqhubekayo obusafufusa kuyibeka njengengxenye ebalulekile emisha emisha yesikhathi esizayo.
Isikhathi sokuthumela: Dec-15-2024